Anna can easily dominate those who do not have the mental conditioning to resist. The novices would require a little more effort to break though the thin layer of dogma drummed into them during training, then say a maid or Watchman. But it is largely down to the individual. Eloise was bored and unfaithful to her vows, making her an easy mark for manipulation. Tabitha too because she had been standing guard all day and her mind had started to wonder as well.
Ordained Knights are difficult to control, due to their intensive training in anti vampire combat.
There are different levels of control, Anna can make her mark see illusions or sound hallucinations, to full complete mental dominance. All it takes is knowing the marks name, with the guard in Chapter 1 pt2 Anna had probably read the female guards mind, gleaned her name and able to influence her thoughts. The same with Eloise and Tabitha.
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I did like the idea of her using the control on the female guard in Chapter 1, part 2. Just a little manipulation to distract the woman away from her concern about Anna's presence. Very good scene.
I also do like that Anna can make people see and hear things that are not there but also can impose complete mental dominance. It is very intriguing that Anna needs to know the woman's name before taking control of her mind. So she obviously needs to read the woman's mind first.
Your description in your comment "Tabitha too because she had been standing guard all day and her mind had started to wonder as well" sets up such a fun scene to imagine since of course in the story Tabitha was already entranced and under Anna's complete control by the time we saw her.
Love to picture pretty young Tabitha standing at her guard post with a look of boredom on her face. Her mind in wondering giving Anna an advantage. Perhaps Tabitha gets a bit of a strange feeling as Anna reads her mind to get her name. She may get a strange look on her face sensing the intrusion into her mind. It doesn't last long as the confused look is replaced by a blank stare as Anna quickly and easily gains total and complete control over Tabitha's mind.
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I think Tabitha could have thought, "Who is she? She's cute. Is she checking me out?" That caused her already dulled mind to open itself fully to Anna. Anna does use her natural good looks to her advantage. Combine that with the Order being made up of young sexually repressed women, in close proximity to each other, its not a surprise that they are open to dominance by Anna.